NbSe2, a true 2D superconductor

_{Figure: Atomically resolved STM image of the NbSe2 surface showing CDW modulation.}

Many-body interactions in solids are at the core of stunning collective electronic phenomena such as CDW order and superconductivity, which are found to exist in some TMD metals in their 3D bulk form. In reduced dimensions, materials usually exhibit remarkable differences in their properties with respect to their 3D bulk counterparts due to quantum confinement effects. In bulk NbSe₂ a CDW sets in at TCDW = 33 K and superconductivity sets in at Tc = 7.2 K. Below 7.2 K these electronic states coexist but their microscopic formation mechanisms in bulk remain controversial after nearly four decades of intense research. Furthermore, the fate of its CDW and superconducting phases in the ultimate single-layer limit has also remained mysterious until now. Writing in Nature Physics, the team has characterized the electronic structure of a single layer of NbSe₂ directly grown on graphene, which experimentally confirms that NbSe₂ undergoes a reduction in the number of electronic bands involved in its collective phases (from three bands in bulk NbSe₂ to just one for single-layer NbSe₂). Despite significant changes in NbSe₂ electronic structure upon dimensional reduction, the authors show that - in stark contrast to recent theoretical predictions - the CDW phase of single-layer NbSe₂ remains unaffected when the material is thinned down to the single-layer limit. The robust 2D character of the CDW in NbSe₂ enables to experimentally rule out two well-known mechanisms proposed to explain the origin of the CDW in NbSe₂. On the contrary to the CDW phase, the material remains a superconductor although with a critical temperature TC = 1.9 K, a significant departure from the behavior of bulk NbSe₂ (TC = 7.2 K).

In summary, these results paint a clear picture of the effects of reduced dimensionality on the CDW and superconducting phases of a model strongly correlated system. This creates exciting new opportunities for directly exploring the interplay between superconductivity and other competing collective phases in 2D.